Capture of sulfur dioxide using sulfur oxydianions: synthesis and characterization of two novel compounds
| dc.contributor.advisor | Passmore, Jack | |
| dc.contributor.author | Richardson, Stephanie | |
| dc.date.accessioned | 2023-03-01T16:49:40Z | |
| dc.date.available | 2023-03-01T16:49:40Z | |
| dc.date.issued | 2013 | |
| dc.date.updated | 2016-07-15T00:00:00Z | |
| dc.description.abstract | One mole equivalent of SO2 reversibly reacts with [N(CH3)4]2SO4(s) to give [N(CH3)4]2S2O6(s) (1) containing the [O3SOSO2]2- ion, shown by Raman and IR to be an isomer of the [O3SSO3]2- dianion. The experimental and calculated (B3PW91/6-311+G(3df)) vibrational spectra are in excellent agreement and the IR spectrum is similar to that of the isoelectronic O3ClOClO2. Crystals of [N(CH3)4]2(O2SO)2SO2•SO2 were isolated from a solution of [N(CH3)4]2SO4 in liquid SO2. The X-ray structure showed that it contained the [(O2SO)2SO2]2- dianion (2). The characterized N(CH3)4 + salts 1 and 2 are the first two members of the (SO4)(SO2)x 2- sulfur oxydianions analogous to the well-known small cation salts of the SO4(SO3)x 2- polysulfates. | |
| dc.description.copyright | © Stephanie Richardson 2013 | |
| dc.description.note | (UNB thesis number) Thesis 9245. (OCoLC)924148057. Electronic only. | |
| dc.description.note | M.Sc. University of New Brunswick, Department of Chemistry, 2013. | |
| dc.format | text/xml | |
| dc.format.extent | xiii, 79 pages : illustrations | |
| dc.format.medium | electronic | |
| dc.identifier.oclc | (OCoLC)924148057 | |
| dc.identifier.other | Thesis 9245 | |
| dc.identifier.uri | https://unbscholar.lib.unb.ca/handle/1882/14536 | |
| dc.language.iso | en_CA | |
| dc.publisher | University of New Brunswick | |
| dc.rights | http://purl.org/coar/access_right/c_abf2 | |
| dc.subject.discipline | Chemistry | |
| dc.subject.lcsh | Sulfur dioxide--Absorption and adsorption. | |
| dc.subject.lcsh | Sulfur dioxide mitigation. | |
| dc.subject.lcsh | Sequestration (Chemistry) | |
| dc.title | Capture of sulfur dioxide using sulfur oxydianions: synthesis and characterization of two novel compounds | |
| dc.type | master thesis | |
| thesis.degree.discipline | Chemistry | |
| thesis.degree.fullname | Master of Science | |
| thesis.degree.grantor | University of New Brunswick | |
| thesis.degree.level | masters | |
| thesis.degree.name | M.Sc. |
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